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Oxetane formation in the photochemical reaction of cyclobutanones with butadiene, cyclopentadiene, and piperylene

✍ Scribed by Dowd, Paul.; Gold, Avram.; Sachdev, Krishna.

Book ID
123610352
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
294 KB
Volume
92
Category
Article
ISSN
0002-7863

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Formation of stilbenes and spiro-oxetane
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✍ Takumi Oshima; Toshikazu Nagai πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 184 KB

The reactions of several phenyldiazomethanes with chloranil gave stilbenes and Spiro-oxetanes at 20Β°C. Stilbenes were major products and the thermodynamically less stable cis-isomers prevailed about 2 to 3 times more than trans-ones depending on the solvents and the substituents of phenyldiazomethan