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Stereoselectivity in the Formation and Radical Reduction of Cyclic Bromoacetals, Key Intermediates for the Synthesis of δ-Hydroxy- and ε-Hydroxy-α-methylcarboxylic Acid Esters.

✍ Scribed by Hajime Nagano; Ayako Mikami; Tomoko Yajima

Publisher
John Wiley and Sons
Year
2003
Weight
133 KB
Volume
34
Category
Article
ISSN
0931-7597

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Stereoselectivity in the formation and r
Stereoselectivity in the formation and radical reduction of cyclic bromoacetals, key intermediates for the synthesis of δ-hydroxy- and ε-hydroxy-α-methylcarboxylic acid esters
✍ Hajime Nagano; Ayako Mikami; Tomoko Yajima 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 144 KB

We report the stereoselectivity in the formation and radical reduction of six-and seven-membered cyclic bromoacetals. The oxidative ring cleavage of the resulting acetals gave the corresponding acyclic d-hydroxyand o-hydroxy-a-methylcarboxylic acid esters.