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Stereoselective Total Synthsis of (±)-Urechitol A

✍ Scribed by Tatsunobu Sumiya; Ken Ishigami; Hidenori Watanabe


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
266 KB
Volume
122
Category
Article
ISSN
0044-8249

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A Stereoselective Total Synthesis of Ver
✍ Biswanath Das; Keetha Laxminarayana; Martha Krishnaiah; Duddukuri Nandan Kumar 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 German ⚖ 163 KB

## Abstract A stereoselective total synthesis of verbalactone has been achieved starting from commercially available hexanal. The sequence involves __Maruoka__ allylation, diastereoselective iodine‐induced electrophillic cyclization, ring opening of epoxide, and __Yamaguchi__ macrolactonization as