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Stereoselective Total Synthesis of Oxylipins: (6 S ,7 E ,9 R ,10 S )-6,9,10-Trihydroxyoctadec-7-enoic Acid and (6 Z ,8 R ,9 R ,10 S )-8,9,10-Trihydroxyoctadec-6-enoic Acid

✍ Scribed by Singh Yadav, Jhillu; Shiva Shankar, Kattela; Srinivas Reddy, Anugu; Subba Reddy, Basi V.


Book ID
121663069
Publisher
John Wiley and Sons
Year
2014
Tongue
German
Weight
228 KB
Volume
97
Category
Article
ISSN
0018-019X

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✍ J.S. Yadav; K. Ramesh; U.V. Subba Reddy; B.V. Subba Reddy; Ahamad Al Khazim Al G 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 319 KB

An expedient stereoselective total synthesis of 18-carbon (+)-(6S,9R,10R)-bovidic acid, isolated from the pelage and skin of a gaur B. frontalis is described using L-proline catalysed sequential a-aminoxylation and Horner-Wadsworth-Emmons olefination of aldehyde, cross metathesis and tandem Sharples