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Stereoselective Total Syntheses of Paecilomycins E and F through a Protecting Group Directed Diastereoselective Intermolecular Nozaki-Hiyama-Kishi (NHK) Reaction

✍ Scribed by Mohapatra, Debendra K.; Reddy, D. Sai; Mallampudi, N. Arjunreddy; Yadav, Jhillu S.


Book ID
125967288
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
351 KB
Volume
2014
Category
Article
ISSN
1434-193X

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Protecting-Group Directed Stereoselectiv
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## Abstract **The cover picture shows** shows how a bulky protecting group directs the intramolecular Nozaki–Hiyama–Kishi reaction to afford exclusively one stereoisomer, whereas a small protecting group directs the reaction to afford both __anti__ and __syn__ isomers in a 2:1 ratio. Details are di