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Stereoselective synthesis of trisubstituted alkenes containing (Z)-allylthio units from the acetates of Baylis–Hillman adducts

✍ Scribed by Yunkui Liu; Danqian Xu; Zhenyuan Xu; Yongmin Zhang

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
228 KB
Volume
19
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

A series of trisubstituted alkenes containing (Z)‐allylthio moieties as key structural units, that is, sodium (Z)‐allyl thiosulfates, symmetrical di(Z‐allyl) sulfides, and di(Z‐allyl) disulfides, unsymmetrical diallyl sulfides were prepared in moderate to good yields via chemical transformations from the acetates of Baylis‐‐Hillman adducts. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:188–198, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20394

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