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Metallic Samarium- and Iodine-Promoted Facile and Efficient Synthesis of Trisubstituted Alkenes from the Acetates of Baylis—Hillman Adducts.

✍ Scribed by Jian Li; Hua Xu; Yongmin Zhang

Publisher
John Wiley and Sons
Year
2005
Weight
20 KB
Volume
36
Category
Article
ISSN
0931-7597

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Stereoselective synthesis of trisubstituted alkenes containing (Z)-allylthio units from the acetates of Baylis–Hillman adducts
✍ Yunkui Liu; Danqian Xu; Zhenyuan Xu; Yongmin Zhang 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 228 KB

## Abstract A series of trisubstituted alkenes containing (__Z__)‐allylthio moieties as key structural units, that is, sodium (__Z__)‐allyl thiosulfates, symmetrical di(__Z__‐allyl) sulfides, and di(__Z__‐allyl) disulfides, unsymmetrical diallyl sulfides were prepared in moderate to good yields via