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Stereoselective Synthesis of the α-Glycoside of a KDO “ C ”-Disaccharide

✍ Scribed by Koketsu, Mamoru; Kuberan, Balagurunathan; Linhardt, Robert J.

Book ID
120009751
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
45 KB
Volume
2
Category
Article
ISSN
1523-7060

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Highly Stereoselective Synthesis of 2-Deoxy-α-glycosides and α-Disaccharides. -Using S-(2-deoxyglycosyl)phosphorodithioates such as (I) as glycosyl donors allows a highly diastereoselective synthesis of 2-deoxyα-glycosides [cf. (III)] and α-disaccharides such as (V). -(BIELAWSKA,