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Stereoselective Synthesis of the Monomeric Unit of SCH 351448

✍ Scribed by J. René Backes; Ulrich Koert

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 191 KB
Volume: 2006
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200600106

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✦ Synopsis

Abstract

The monomeric unit of the macrodiolide SCH 351448 has been synthesized from three building blocks. Strategic disconnections were chosen between C21–C22 (Wittig) and C10–C11 (stereoselective aldol). The cis configuration of both 2,6‐disubstituted tetrahydropyran rings was established by a stereoselective cationic reduction. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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