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Stereoselective Synthesis of Tetrahydropyran-2,4-diols by a Simple Domino Aldol-Aldol Hemiacetal One-Pot Reaction

✍ Scribed by Michael Schmittel; Manas K. Ghorai; Andreas Haeuseler; Wolfgang Henn; Thomas Koy; Rolf Söllner

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
148 KB
Volume
1999
Category
Article
ISSN
1434-193X

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✦ Synopsis

A new metal-directed (Ti, Zr, Al, In, Sn) domino aldol-aldol highly stereoselective de-novo synthesis of tetrahydropyran-2,4-diols containing five stereogenic centers. hemiacetal reaction is presented that can be used for the [a] FB 8 Ϫ OC 1 (Chemie-Biologie) UniversitätϪGH Siegen to NMR-spectroscopic and X-ray analysis, [11] compound 3

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