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Stereoselective Synthesis of syn-β-Amino Propargylic Ethers: Application to the Asymmetric Syntheses of (+)-β-Conhydrine and (−)-Balanol

✍ Scribed by Julien Louvel; Fabrice Chemla; Emmanuel Demont; Franck Ferreira; Alejandro Pérez-Luna; Arnaud Voituriez


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
413 KB
Volume
353
Category
Article
ISSN
1615-4150

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Synthesis and Applications of Nonracemic β-Amino Aldehydes to the Asymmetric Synthesis of Piperidines: (+)-Dihydropinidine. -A new method to synthesize chiral building blocks, i.e. the stable N-protected β-aminoaldehydes (VI), in 4 steps is reported. They are applied in the synthesis of the piperid