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Stereoselective Synthesis of Substituted Bicyclo-[3.3.1]-nonan-9-ones by Additions of Enamines of Cyclohexanones to 4-Ethoxy-1,1,1-trifluorobut-3-ene-2-one

✍ Scribed by Rebecca J Andrew; John M Mellor; Gillian Reid


Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
140 KB
Volume
56
Category
Article
ISSN
0040-4020

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ChemInform Abstract: A Practical Synthes
✍ C. TAESCHLER; T. S. SORENSEN πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 2 views

A Practical Synthesis of Bicyclo[3.3.1]nonan-9-one. -A new protocol for the synthesis of title compound (VII) is presented. It uses inexpensive and readily available reagents, involves no purification of intermediates and can be carried through on a β‰ˆ20 g product scale in 47% yield. -(TAESCHLER,