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Stereoselective Synthesis of Seven-Membered Carbocycles from 2-Amino-1,3-butadienes and Vinyl Chromium Fischer-Type Carbenes

✍ Scribed by Barluenga, Jose; Aznar, Fernando; Martin, Alfredo; Vazquez, Jesus T.


Book ID
127099517
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
938 KB
Volume
117
Category
Article
ISSN
0002-7863

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## Abstract Fischer carbene complexes react with 4‐unsubstituted 1‐amino‐1,3‐dienes to give different carbocyclization products depending on the nature of the carbene complex and on the substitution pattern of the aminodiene. Thus, the reaction of arylcarbene chromium complexes and 1‐aminodienes di