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Stereoselective Synthesis of Polypropionate Units and Heterocyclic Compounds by Cyclopropylcarbinol Ring-Opening with Mercury(II) Salts

✍ Scribed by Christophe Meyer; Nicolas Blanchard; Magali Defosseux; Janine Cossy


Publisher
John Wiley and Sons
Year
2004
Weight
52 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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## Abstract Rhodium(II)‐catalyzed reactions of diazodicarbonyl compounds with a variety of conjugated dienes have been examined. These reactions provide a simple and rapid route to dihydrofurans and dihydrooxepines with a variety of substituents on the ring. The formation of these products is inter