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Efficient Synthesis of Five- and Seven-Membered-Ring Heterocycles by Rhodium(II)-Catalyzed [3 + 2] and [3 + 4] Cycloaddition of Diazodicarbonyl Compounds with Conjugated Dienes.

✍ Scribed by Yong Rok Lee; Jae Cheol Hwang


Publisher
John Wiley and Sons
Year
2005
Weight
39 KB
Volume
36
Category
Article
ISSN
0931-7597

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Diastereoselective Synthesis of Five- an
✍ JosΓ© Barluenga; Jorge Alonso; Francisco J. FaΓ±anΓ‘s πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 210 KB πŸ‘ 1 views

## Abstract β‐Substituted alkenylcarbene complexes react with methyl ketone lithium enolates to give different carbocyclization products depending on the structure of the lithium enolate, on the metal of the carbene complex, and on the reaction media. Thus, the reactions of aryl and alkyl methyl ke