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Stereoselective Synthesis of Polyoxamic Acid from (R)-Phenylglycine

✍ Scribed by G Veeresa; Apurba Datta

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
549 KB
Volume
39
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Stereoselective Syn
ChemInform Abstract: Stereoselective Synthesis of Polyoxamic Acid from (R)-Phenylglycine.
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Polyoxamic acid , 2-amino-2-deoxy-L-xylonic acid, is synthetized by thiophenoxide opening of a five-carbon chiral hydroxylated aziridine easily derived from L-arabinose. The formation of the carboxy group resulted lrom a Pummerer reaction. Polyoxins belong to a group of antifungal antibiotics produc

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In the course of our study directed toward the total synthesis of Polyoxin J which is a member of the unique antibiotics, Polyoxin complex, 1) we have succeeded in syntheses of its constituent fragments; namely l-( '-amino-5'-deoxy-B-Dallofuranuronosyl)-thymine ') and 2-amino-2-deoxy-L-xylonic acid