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Stereoselective Synthesis of Oligo-α-(2,8)-Sialic Acids

✍ Scribed by Tanaka, Hiroshi; Nishiura, Yuji; Takahashi, Takashi

Book ID
120571428
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
60 KB
Volume
128
Category
Article
ISSN
0002-7863

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A novel donor for stereoselective α-sial
A novel donor for stereoselective α-sialylation; efficient synthesis of an α(2–8)-linked bis-sialic acid unit
✍ Nafizal Hossain; Göran Magnusson 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 252 KB

The novel sialyl donor methyl [ethyl 5-(N,N-diacetyl)-4,7,8,9-tetra-O-acetyl-2-thio-3thiophenyl-2,3,5-trideoxy-D-erythro-o,-L-gluco-2-nonulopyranosid]onate (2) was synthesized by Nacetylation of the corresponding 5-acetamido compound 1. a-Sialylation of mono-and disaccharide aglycons, having one or