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Stereoselective Synthesis of Methyl 15,16-Epoxypimarates

✍ Scribed by Miguel, Bernadette Arreguy-San; Taran, Martine; Picard, Philippe; Delmond, Bernard

Book ID: 120184260
Publisher: Taylor and Francis Group
Year: 1989
Tongue: English
Weight: 323 KB
Volume: 19
Category: Article
ISSN: 0039-7911
DOI: 10.1080/00397918908051018

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## Abstract The cationic cyclization of 2‐[6‐(__m__‐methoxyphenyl)‐(__E__)‐3‐hexenyl]‐3,5‐dimethyl‐2‐cyclopentenol (**3**) was investigated. Exclusive formation of 1‐ and 3‐methoxy‐15α,17‐dimethyl‐1,3,5(10), 13(17)‐gonatetraene (**4** and **5**) was observed, indicating complete stereoselectivity i