## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
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Stereoselective Synthesis of (-)-Malyngolide, (+)-Malyngolide and (+)-Tanikolide Using Ring-Closing Metathesis.
β Scribed by Miguel Carda; Santiago Rodriguez; Encarnacion Castillo; Alejandro Bellido; Santiago Diaz-Oltra; J. Alberto Marco
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 38 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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The stereoselective synthesis of the naturally occurring lactones osmundalactone (-)-1 and muricatacin (-)-2 is described. The key steps in each synthesis are the stereoselective addition of a Grignard reagent to a suitably protected Ξ±hydroxy aldehyde and a ring-closing metathesis.