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Stereoselective synthesis of hydroxy octadecatrienoic acids. The self defensive substances in rice plant

โœ Scribed by A.V.Rama Rao; E.Rajarathnam Reddy


Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
135 KB
Volume
27
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Convenient

synthesis of 16-hydroxy-9Z,122,14E-octadecatrienoic acid (L) and 9hydroxy-lOE,12Z,15Z-octadecatrienoic acid (2) the self defensive substances in rice plant against rice blast disease are described.


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Stereoselective synthesis of the hydroxy
โœ Akiyoshi Kawai; Osamu Hara; Yasumasa Hamada; Takayuki Shioiri ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 222 KB

The hydroxy amino acid moiety of AI-77-B (1) has been prepared as its protected form 2 from the (R)-glyceric acid derivative 3 in an efficiently stereoselective manner through the direct C-acylation using diphenyl phosphorazidate and the hydroxy-directed hydrogenation. Al-77-B having a unique gastr