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Stereoselective synthesis of glycoclusters using an olefin metathesis and Sharpless dihydroxylation sequence

✍ Scribed by Romyr Dominique; René Roy

Book ID
104232227
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
108 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

An asymmetric synthesis of a-D-mannopyranoside-based glycoclusters has been accomplished using olefin metathesis and Sharpless asymmetric dihydroxylation reactions as key steps. Access to a family of dimeric and tetrameric glycoclusters having chiral core structures was achieved to investigate topographical arrays of carbohydrate-protein binding interactions.

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