Stereoselective Synthesis of Furans by the Pd-Catalyzed Oshima—Utimoto Reaction.
✍ Scribed by Michael A. Evans; James P. Morken
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 37 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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## Abstract The intramolecular iron‐catalyzed ring expansion reaction of epoxyalkenes was investigated with a preformed iron(salen) [Fe(Salen)] complex. The formal insertion of the alkene into the epoxide generated hexahydrocyclopenta[__c__]furan derivatives in moderate to good yields and diastereo