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Stereoselective Synthesis of 1,4-Bifunctional Compounds by Regioselective Pd-Catalyzed Allylic Substitution Reaction.

✍ Scribed by Naoyoshi Maezaki; Yuki Hirose; Tetsuaki Tanaka

Publisher
John Wiley and Sons
Year
2004
Weight
37 KB
Volume
35
Category
Article
ISSN
0931-7597

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Practical Synthesis of Allylic Silanes from Allylic Esters and Carbamates by Stereoselective Copper-Catalyzed Allylic Substitution Reactions
✍ Martin Oestreich; Gertrud Auer πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 87 KB πŸ‘ 2 views

The first copper-catalyzed allylic substitution reactions of allylic acetates and carbamates employing a bis(triorganosilyl)zinc reagent are reported. This novel procedure avoids the use of stoichiometric amounts of copper salts which are usually mandatory with this chemistry. Application of this me