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Stereoselective synthesis of (E)-3,3-diaryl and (E)-3-aryl-3-aryloxy allylamines and allylalcohols from trans-cinnamyl chloride and alcohol

โœ Scribed by Limberger, Jones; Claudino, Thiago S.; Monteiro, Adriano L.

Book ID
127290256
Publisher
The Royal Society of Chemistry
Year
2014
Tongue
English
Weight
323 KB
Volume
4
Category
Article
ISSN
2046-2069

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Stereo- and regioselective synthesis of
Stereo- and regioselective synthesis of 1,3-diaryl-3-chloro-1-propanols via the reaction of aryl aldehydes with styrene and (E)-ฮฒ-methylstyrene
โœ George W. Kabalka; Zhongzhi Wu; Yuhong Ju ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 100 KB

Reactions of aryl aldehydes with styrene and (E)-b-methylstyrene in the presence of phenylboron dichloride regioselectively generate 1,3-diaryl-3-chloro-1-propanols and 1,3-diaryl-3-chloro-2-methyl-1-propanols in good to excellent yields with high stereoselectivity.