𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Stereoselective synthesis of azasugar thioglycosides

✍ Scribed by M.Angeles Pradera; Francisco J. Sayago; José M. Illangua; Consolación Gasch; José Fuentes

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
265 KB
Volume
44
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Bicyclic (2-oxapyrrolizidines) and monocyclic (piperidine) azasugar ethyl thioglycosides, a new type of azasugar derivative, are stereoselectively prepared from suitable glycosylenamines, through anhydroazasugar derivatives.

📜 SIMILAR VOLUMES

A norbornyl route to azasugars: stereose
A norbornyl route to azasugars: stereoselective synthesis of isofagomine analogues
✍ Goverdhan Mehta; Narinder Mohal 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 162 KB

A stereoselective synthesis of new isofagomine analogues has been achieved from a suitably functionalized cyclopentene intermediate extracted from the norbornyl framework. Double reductive amination or inter-and intramolecular N-alkylations are the key steps in constructing the piperidine ring. Isof