Stereoselective Synthesis of Aza Analogues of Isoaltholactone and Goniothalesdiol – New Applications of the Heck–Matsuda Reaction
✍ Scribed by Angélica Venturini Moro; Marcelo Rodrigues dos Santos; Carlos Roque D. Correia
- Book ID
- 102832059
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 589 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-193X
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📜 SIMILAR VOLUMES
The stereoselective synthesis of structurally simplified heptacyclic cephalostatin analogues 2, 3, 18-21, 31, 32 and 33 by multiple Heck reactions is described. The key step of the synthesis is a selective Heck reaction of hydrindene 7 with 12 and 25, respectively at the vinyl bromide moiety followe
Heck reactions of unsaturated amino acid building blocks are described which allow access to homo-and bishomophenylalanine derivatives and to g,d-unsaturated amino acids. Preliminary synthetic studies utilising this chemistry for the preparation of pyrrololine and deoxypyrrololine analogues are also
## Abstract Review: ca. 130 refs.