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Stereoselective Synthesis of 2-Alkenylaziridines and 2-Alkenylazetidines by Palladium-Catalyzed Intramolecular Amination of α- and β-Amino Allenes

✍ Scribed by Ohno, Hiroaki; Anzai, Miyuki; Toda, Ayako; Ohishi, Shinya; Fujii, Nobutaka; Tanaka, Tetsuaki; Takemoto, Yoshiji; Ibuka, Toshiro

Book ID
120019038
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
177 KB
Volume
66
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Stereoselective Syn
ChemInform Abstract: Stereoselective Synthesis of 2-Alkenylaziridines and 2-Alkenylazetidines by Palladium-Catalyzed Intramolecular Amination of α- and β-Amino Allenes.
✍ Hiroaki Ohno; Miyuki Anzai; Ayako Toda; Shinya Ohishi; Nobutaka Fujii; Tetsuaki 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Palladium-catalyzed regio- and stereosel
Palladium-catalyzed regio- and stereoselective synthesis of N-protected 2,4-dialkylated azacyclobutanes from amino allenes
✍ Miyuki Anzai; Ayako Toda; Hiroaki Ohno; Yoshiji Takemoto; Nobutaka Fujii; Toshir 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 275 KB

Palladium-catalyzed reaction of N-arylsulfonyl-l-alkyl-3,4-dienylamines with an aryl iodide in the presence of potassium carbonate in DMF at around 70°C affords most predominantly the 2,4-cis-disubstituted azacyclobutanes bearing an aryl group on the double bond in good yields.