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Stereoselective Synthesis and Reactivity of Dienyl Zirconocene Derivatives

✍ Scribed by Nicka Chinkov; Swapan Majumdar; Ilan Marek


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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A new class of organometallic polymer having a backbone of conjugated Poly-yne and Zr-metal atoms has been prepared. Trichloroethylene (TCE) and Hexachlorobutadiene (HCB) are quantitatively converted by n-butyllithium to dilithioacetylene (LiC'CLi) and dilithiodiacetylene (LiOC'COC'COLi) respectivel