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Stereoselective Synthesis and Determination of the Cytotoxic Properties of Spicigerolide and Three of Its Stereoisomers

✍ Scribed by Falomir, Eva; Murga, Juan; Ruiz, Purificación; Carda, Miguel; Marco, J. Alberto; Pereda-Miranda, Rogelio; Fragoso-Serrano, Mabel; Cerda-García-Rojas, Carlos M.

Book ID
126197467
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
120 KB
Volume
68
Category
Article
ISSN
0022-3263

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Altholactone 1 and (+)-7-epi-altholactone 3 were constructed from Dgulonolactone whereas their respective enantiomers (-)-altholactone 2 and (-)J-epialtholactone 4 were synthesised from D-mannose, involving stereocontrolled reduction of the lactols 21 and 12 as a key step. 'I-epi-altholactone 3, an