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Stereoselective Synthesis and Absolute Configuration Determination of Xylariolide A

✍ Scribed by Botubol, José Manuel; Macías-Sánchez, Antonio J.; Collado, Isidro G.; Hernández-Galán, Rosario

Book ID
120188159
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
643 KB
Volume
2013
Category
Article
ISSN
1434-193X

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✍ Masaki Takahashi; Takamasa Suzuki; Jolanta Wierzejska; Tetsuya Sengoku; Hidemi Y 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 314 KB

The first asymmetric synthesis of (+)-amphiasterin B4 was completed from a known (S)-b-benzyloxy-clactone. Comparison with the spectroscopic properties reported for authentic material has given a clear indication as to the absolute stereochemistry of the natural amphiasterin B4.