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Stereoselective Synthesis of (+)-Paeonilide (I) and Confirmation of Its Absolute Configuration.

✍ Scribed by Chenying Wang; Hongbin Zhang; Jikai Liu; Yanhua Ji; Zhihui Shao; Liang Li


Publisher
John Wiley and Sons
Year
2006
Weight
9 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract Starting from 4,4‐dimethyl‐2‐cyclohexenone, an enantioselective synthesis of (–)‐isopisiferin has been accomplished in 15 steps with an overall yield of 11.4 %. This work not only provides synthetic evidence for confirming the absolute configuration of natural isopisiferin itself, but a