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Stereoselective syntheses of the rhizoxin C(1)C–(9) and C(12)–C(26) subunits

✍ Scribed by Steven D. Burke; Jian Hong; Andrew P. Mongin

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
324 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

Stereoselective syntheses of the C(l)-C(9) and C(12)-C(26) subunits of the macrolide antitumor agent rhizoxin are described. Chelation-controlled Ireland-Claisen rearrangement, stereoselective Horner-Wadsworth-Emmons reactions and a thermodynamically-controlled diastereotopic group differentiation are featured.

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