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Stereoselective syntheses of 11-α-methoxycurvularin and 11-β-methoxycurvularin

✍ Scribed by G. Venkateswar Reddy; R. Sateesh Chandra Kumar; K. Suresh Babu; J. Madhusudana Rao

Book ID
108285561
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
258 KB
Volume
50
Category
Article
ISSN
0040-4039

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Stereoselective Total Synthesis of (11β)
Stereoselective Total Synthesis of (11β)-11-Methoxycurvularin
✍ Karuturi Rajesh; Vangaru Suresh; Jondoss Jon Paul Selvam; Dokuburra Chanti Babu; 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 German ⚖ 164 KB

## Abstract A simple and highly efficient stereoselective total synthesis of (11__β__)‐11‐methoxycurvularin (**5**), a polyketide natural product, was achieved. The synthesis commenced with a Cu‐mediated regioselective opening of (2__S__)‐2‐methyloxirane (**6**) and comprised a __Keck__ asymmetric