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Stereoselective Reduction of Benzils: A New Convenient Route to Enantiomerically Pure 1,2-Diarylethanediols

✍ Scribed by Prasad, K. R. K.; Joshi, N. N.


Book ID
121466450
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
95 KB
Volume
61
Category
Article
ISSN
0022-3263

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A new route to enantiopure syn and anti 1,2-diols is described from oxalyl-di-(Nmethyl-N-methoxyamide) via the corresponding ~-ketosulfoxide. This is the first report of the stereoselective reduction ofaT--keto-~-hydroxysulfoxide.