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Stereoselective reactions of alkenylpyranosides: the effect of double bond geometry on conformation

✍ Scribed by DeNinno, Michael P.; Danishefsky, Samuel J.; Schulte, Gayle.

Book ID
115506972
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
696 KB
Volume
110
Category
Article
ISSN
0002-7863

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In the crystal structure of methyl (Z)-8,9-dideoxy-l,2:3,4:6,7-tri-0-isopropylidene-a-~-fhreo-ogalacto-dec-8-enopyranuronate (lo), the allylic system adopts an eclipsed conformation with the smallest group, H-7, at the adjacent stereocentre eclipsing the olefinic double bond. The allylic system of m