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Effect of double bond geometry in sphingosine base on the antioxidant function of sphingomyelin

โœ Scribed by Papasani V. Subbaiah; Debajit Sircar; Ravi S. Lankalapalli; Robert Bittman


Book ID
116178311
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
849 KB
Volume
481
Category
Article
ISSN
0003-9861

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The effect of double-bond geometry on th
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In the crystal structure of methyl (Z)-8,9-dideoxy-l,2:3,4:6,7-tri-0-isopropylidene-a-~-fhreo-ogalacto-dec-8-enopyranuronate (lo), the allylic system adopts an eclipsed conformation with the smallest group, H-7, at the adjacent stereocentre eclipsing the olefinic double bond. The allylic system of m