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Stereoselective Preparation of Deuteriated Dienes by Ring Fragmentation of Metalated Cyclopropylcarbinols.

✍ Scribed by Elinor Zohar; Mirit Ram; Ilan Marek


Publisher
John Wiley and Sons
Year
2004
Weight
20 KB
Volume
35
Category
Article
ISSN
0931-7597

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Generation of methylenephosphine oxides
✍ GyΓΆrgy Keglevich; KΓ‘lmΓ‘n ÚjszΓ‘szy; Louis D. Quin; GyΓΆngyi S. Quin πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 410 KB πŸ‘ 1 views

## Differential thermal analysis and differential scanning calorimetry showed that the title compounds decomposed at 240-260Β°C with release of the fragment RP(0) = CH,. Mass spectral studies also showed this to be a fragmentation pathway. The extruded methylenephosphine oxide could be trapped with