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Stereoselective Preparation and Reactions of Configurationally Defined Dialkylzinc Compounds

โœ Scribed by Andreas Boudier; Christophe Darcel; Felix Flachsmann; Laurent Micouin; Martin Oestreich; Paul Knochel

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
311 KB
Volume
6
Category
Article
ISSN
0947-6539

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Asymmetric induction that arises from organolithium substrates complexed to chiral ligands has emerged as an efficient and powerful method. Since Hoppe et al. showed a high enantioenrichment could be achieved in a lithiation reaction to provide a-oxygen-substituted dipole-stabilized carbanions, [1]