Asymmetric induction that arises from organolithium substrates complexed to chiral ligands has emerged as an efficient and powerful method. Since Hoppe et al. showed a high enantioenrichment could be achieved in a lithiation reaction to provide a-oxygen-substituted dipole-stabilized carbanions, [1]
✦ LIBER ✦
Enantioselective Reactions of Configurationally Unstable α-Thiobenzyllithium Compounds
✍ Scribed by Shuichi Nakamura; Ryo Nakagawa; Yoshihiko Watanabe; Takeshi Toru
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 81 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0044-8249
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A r 3 B A A r 3 B A ~r 3 sensitivity of sensitized films is due to the decrease in Tg of PMMA on sensitizing with LMG. Introduction of anionic states in PMMA by addition of LMG results in increase in conductivity of these films.