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Stereoselective palladium-catalyzed allylic alkylations of peptideamide enolates

✍ Scribed by Datta, Swarup ;Kazmaier, Uli


Book ID
118209601
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
246 KB
Volume
9
Category
Article
ISSN
1477-0520

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## Abstract Lithium and magnesium enolates of cyclohexanone undergo palladium‐catalyzed allylic alkylations under mild conditions. Diastereoselectivity and enantioselectivity are observed when the diphenyl‐ and dimethyl‐substituted allylic substrates **1a** and **1b** are reacted with cyclohexanone

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.