Stereoselective palladium-catalyzed allylic alkylations of peptideamide enolates
β Scribed by Datta, Swarup ;Kazmaier, Uli
- Book ID
- 118209601
- Publisher
- Royal Society of Chemistry
- Year
- 2011
- Tongue
- English
- Weight
- 246 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1477-0520
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## Abstract Lithium and magnesium enolates of cyclohexanone undergo palladiumβcatalyzed allylic alkylations under mild conditions. Diastereoselectivity and enantioselectivity are observed when the diphenylβ and dimethylβsubstituted allylic substrates **1a** and **1b** are reacted with cyclohexanone
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