๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Stereoselective electrochemical transformation of 4-substituted cyclohexanones into cis-5-substituted 2,2-dimethoxycyclohexanols

โœ Scribed by M. N. Elinson; S. K. Feducovich; D. E. Dmitriev; A. S. Dorofeev; A. N. Vereshchagin; G. I. Nikishin

Book ID
110402382
Publisher
Springer
Year
2002
Tongue
English
Weight
370 KB
Volume
51
Category
Article
ISSN
1573-9171

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Stereoselective electrochemical transfor
Stereoselective electrochemical transformation of 4-substituted cyclohexanones into cis-5-substituted-2,2-dimethoxycyclohexanols
โœ Michail N. Elinson; Sergey K. Feducovich; Dmitry E. Dmitriev; Alexander S. Dorof ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 62 KB

Electrolysis of 4-substituted cyclohexanones in methanol in the presence of sodium halides in an undivided cell results in the stereoselective formation of cis-5-substituted-2,2-dimethoxycyclohexanols in 70-80% yield.

Stereoselective transformation of pyrazi
Stereoselective transformation of pyrazinones into substituted analogues of cis-5-amino-6-oxo-2-piperidinemethanol and cis-5-amino-2-piperidinemethanol
โœ Joeri Rogiers; Wim M De Borggraeve; Suzanne M Toppet; Frans Compernolle; Georges ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 402 KB

Various analogues of cis-5-amino-6-oxo-2-piperidinemethanol and cis-5-amino-2-piperidinemethanol have been prepared via Diels -Alder reaction of substituted pyrazinones with ethene followed by acid methanolysis of the bridged lactam adducts. Further reduction of the resulting methyl 2-piperidinecarb