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Stereoselective Coupling of Prochiral Radicals with a Chiral C 2 -Symmetric Nitroxide

โœ Scribed by Braslau, Rebecca; Naik, Neeta; Zipse, Hendrik


Book ID
120355312
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
511 KB
Volume
122
Category
Article
ISSN
0002-7863

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Planar chiral C2-symmetric bisferrocenes
โœ Nobukazu Taniguchi; Motokazu Uemura ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 230 KB

Planar chiral or-substituted ferrocenecarboxaldehydes were treated with samarium diiodide to give stereoselectively pinacol coupling products with a threo-configurafion in good yields. The resulting dihydroxyl of the product was substituted with stereochemical inversion by an SNI reaction.