Stereoselective conversion of allylic alcohols to n-acyl-trans-4,5-dialkyloxazolidines.
โ Scribed by Kenn E Harding; Randall Stephens; Donald R Hollingsworth
- Book ID
- 104242408
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 143 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
-oxazolones in the presence of allylic alcohols resulted in a novel one-pot transformation to Z,S-unsaturated N-benzoyl amides via decarbonylation, nucleophilic addition of allylic alcohols, photoinduced hydrogen transfer and the Claisen rearrangement.
Photoinduced One-Pot Transformation of 2-Phenyl-4-ethylidene-5(4H)-oxazolone and Allylic Alcohols to ฮณ,ฮด-Unsaturated N-Benzoyl Amides. -Photolysis of a mixture of oxazolone (I) and allylic alcohols (II) results in a novel formation of N-benzoyl amides (III). The conversion proceeds via decarbonylat