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Photoinduced one pot transformation of 2-phenyl-4-ethylidene-5(4H)-oxazolone and allylic alcohols to γ, δ-unsaturated N-benzoyl amides

✍ Scribed by Bong Sen Park; Chul Min Oh; Keun Ho Chun; Jong Ook Lee

Book ID
104260342
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
216 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

-oxazolones in the presence of allylic alcohols resulted in a novel one-pot transformation to Z,S-unsaturated N-benzoyl amides via decarbonylation, nucleophilic addition of allylic alcohols, photoinduced hydrogen transfer and the Claisen rearrangement.

📜 SIMILAR VOLUMES

ChemInform Abstract: Photoinduced One-Po
ChemInform Abstract: Photoinduced One-Pot Transformation of 2-Phenyl-4-ethylidene-5(4H)-oxazolone and Allylic Alcohols to γ,δ-Unsaturated N-Benzoyl Amides.
✍ Bong Ser Park; Chul Min Oh; Keun Ho Chun; Jong Ook Lee 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

Photoinduced One-Pot Transformation of 2-Phenyl-4-ethylidene-5(4H)-oxazolone and Allylic Alcohols to γ,δ-Unsaturated N-Benzoyl Amides. -Photolysis of a mixture of oxazolone (I) and allylic alcohols (II) results in a novel formation of N-benzoyl amides (III). The conversion proceeds via decarbonylat