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Stereoselective Bulk Polymerization of Racemic Lactide for Stereoblock Poly(racemic lactide) Using an Achiral Aluminum Complex

✍ Scribed by Ishii, Ryohei; Nomura, Nobuyoshi; Kondo, Tadao

Book ID
124152346
Publisher
Nature Publishing Group
Year
2004
Tongue
English
Weight
97 KB
Volume
36
Category
Article
ISSN
0032-3896

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The polymerization of racemic lactide with a racemic aluminum alkoxide catalyst is reported. Microstructural analysis of the polymer produced with 1 H NMR spectroscopy revealed that an isotactic stereoblock poly(lactic acid) formed, where each enantiomerically pure block contained an average of 11 l