The polymerization of racemic lactide with a racemic aluminum alkoxide catalyst is reported. Microstructural analysis of the polymer produced with 1 H NMR spectroscopy revealed that an isotactic stereoblock poly(lactic acid) formed, where each enantiomerically pure block contained an average of 11 l
✦ LIBER ✦
Stereoselective Ring-Opening Polymerization of a Racemic Lactide by Using Achiral Salen– and Homosalen–Aluminum Complexes
✍ Scribed by Nobuyoshi Nomura; Ryohei Ishii; Yoshihiko Yamamoto; Tadao Kondo
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 784 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0947-6539
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