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Stereoselective and regioselective ene reactions of methyl .alpha.-chloroacrylate

✍ Scribed by Snider, Barry B.; Duncia, John V.


Book ID
120156325
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
368 KB
Volume
102
Category
Article
ISSN
0002-7863

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Regio- and Stereoselective Ene and Tande
✍ Giuseppe Capozzi; Marco Fragai; Stefano Menichetti; Cristina Nativi πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 300 KB πŸ‘ 1 views

2,4-Dioxopentane-3-thione 1a reacts as an enophile with ethers or allenes as ene counterparts, the formation of the thiophilic adduct is followed by a fast cycloaddition reaction various allyl derivatives affording thiophilic ene adducts as single regioisomers with high (E) stereoselectivity. Using