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Ene Reactions of Alkynes for the Stereoselective Synthesis of Allylamines

✍ Scribed by Dipl.-Ing. Armin R. Ofial; Prof. Herbert Mayr

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
359 KB
Volume
36
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES

Transition structure for the retroene-ty
Transition structure for the retroene-type elimination reaction of propene from allylamines
✍ Leonardo Rodriguez; Wasdin MuΓ±oz; Gonzalo Martin; Edgar Ocando-Mavarez πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 145 KB πŸ‘ 1 views

The transition-state geometries of retroene elimination reactions of propene from allylamines have been calculated by using the semiempirical AM1 method. The most favored geometry resembles a half chair or a flattened boat. It is also found that the transition states are of polar character and that