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Stereoselective Amine Addition to Six-Membered Cyclic Nitronates Promoted by Silyl Triflate

✍ Scribed by Mikhaylov, Andrey A.; Dilman, Alexander D.; Khomutova, Yulia A.; Arkhipov, Dmitry E.; Korlyukov, Alexander A.; Ioffe, Sema L.


Book ID
120886287
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
922 KB
Volume
2013
Category
Article
ISSN
1434-193X

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## Abstract An efficient methodology for the synthesis of α‐aminophosphonates has been developed taking advantage of the __tert__‐butyldimethylsilyl triflate activated addition of diethyl phosphite to __N__‐benzyl nitrones derived from chiral α‐alkoxy and α‐(Boc‐amino) aldehydes. The stereoselectiv