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Stereoselective aldol reactions via titanium enolates

✍ Scribed by Patrick J. Murphy; Garry Procter; Andrew T. Russell


Book ID
108382915
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
189 KB
Volume
28
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Stereoselective aldol reactions. Reactio
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By proper choice of counterion, the enolate of n5-CpFe(CO)(PPh3)COCH3 will react with aldehydes to form the aldol products with high stereoselectivity. Chiral iron acyls, n5-CpFe(CO)(PPh3)COCH2R, can be deprotonated by strong base to the corresponding enolates that then react with organic electrophi