Stereoselective aldol reactions via titanium enolates
β Scribed by Patrick J. Murphy; Garry Procter; Andrew T. Russell
- Book ID
- 108382915
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 189 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstracf The cbml ester 7 was evoked under TiC/JEf,N cond@ons and reacted wth aldehydes to give moderas to good sfereoselectrvrbes The c/m/ auxhary group can be removed by ample sapon~ffcafm and recovered
Aldol Reactions provides a comprehensive up-to-date overview of aldol reactions including application of different metal enolates; catalytic aldol additions catalyzed by different Lewis acids and Lewis bases; enantioselective direct aldol additions; antibodies and enzyme catalyzed aldol additions an
By proper choice of counterion, the enolate of n5-CpFe(CO)(PPh3)COCH3 will react with aldehydes to form the aldol products with high stereoselectivity. Chiral iron acyls, n5-CpFe(CO)(PPh3)COCH2R, can be deprotonated by strong base to the corresponding enolates that then react with organic electrophi